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Masayuki Inoue
Original Papers
  1. M. Inoue, N. Shinohara, S. Tanabe, T. Takahashi, K. Okura, H. Itoh, Y. Mizoguchi, M. Iida, N. Lee, S. Matsuoka, "Total synthesis of the large non-ribosomal peptide polytheonamide B," Nature Chem. AOP.
  2. S. Kamijo, Y. Amaoka, M. Inoue, "Manganese-Catalyzed Direct Oxidation of Methyl Ethers to Ketones," Chem. Asian J. Early view.
  3. S. Kamijo, T. Hoshikawa, M. Inoue, "Regio- and Stereoselective Acylation of Saturated Carbocycles via Norrish-Yang Photocyclization," Tetrahedron Lett. 2010, 51, 872-874.
  4. K. Okura, S. Matsuoka, R. Goto, M. Inoue, "The Twisted Side Chain of Antillatoxin is Important for Potent Toxicity: Total Synthesis and Biological Evaluation of Antillatoxin and Analogues," Angew. Chem. Int. Ed. 2010, 49, 329-332.
  5. K. Matoba, T. Nara, T. Aoki, T. Honma, A. Tanaka, M. Inoue, S. Matsuoka, D. Inaoka, K. Kita, S. Harada, "Crystallization and Preliminary X-ray Analysis of Aspartate Transcarbamoylase from the Parasitic Protist Trypanosoma Cruzi," Acta Crystallogr., Sect. F: Struct. Biol. Cryst. Commun. 2009, F65, 933.
  6. S. Kasuya, S. Kamijo, M. Inoue, "Direct Construction of 1,3-Diaxial Diol Derivatives by C-H Hydroxylation," Org. Lett. 2009, 11, 3630-3632.
  7. S. Ogawa, D. Urabe, Y. Yokokura, H. Arai, M. Arita, M. Inoue, "Total Synthesis and Bioactivity of Resolvin E2," Org. Lett. 2009, 11, 3602-2605.
  8. M. Inoue, N. Lee, T. Tsumuraya, I. Fujii, M. Hirama, "Use of Monoclonal Antibodies as an Effective Strategy for Treatment of Ciguatera Poisoning," Toxicon 2009, 53, 802-805.
  9. K. Yamaoka, M. Inoue, K. Miyazaki, M. Hirama, C. Kondo, E. Kinoshita, H. Miyoshi, I. Seyama, "Synthetic Ciguatoxins Selectively Activate Nav1.8-Derived Chimeric Sodium Channels Expressed in HEK293 Cells," J. Biol. Chem. 2009, 284, 7597-7605.
  10. K. Hagiwara, M. Himuro, M. Hirama, M. Inoue, "A Concise Route to C2-symmetric Tricyclic Skeleton of Ryanodine," Tetrahedron Lett. 2009, 50, 1035-1037.
  11. N. Lee, M. Inoue, M. Hirama, "Design and Synthesis of a Conformationally Restricted Analogue of the EFGH-Ring System of Ciguatoxin," Heterocycles 2009, 79, 325-330.
  12. M. Inoue, N. Lee, K. Miyazaki, T. Usuki, S. Matsuoka, M. Hirama "Critical Importance of the Nine-Membered F Ring of Ciguatoxin for Potent Bioactivity: Total Synthesis and Biological Evaluation of F-Ring-Modified Analogues" Angew. Chem. Int. Ed. 2008, 47, 8611-8614.
  13. M. Ui, Y. Tanaka, T. Tsumuraya, I. Fujii, M. Inoue, M. Hirama, K. Tsumoto, "How Protein Recognizes Ladder-like Polycyclic Ethers: Interactions between Ciguatoxin (CTX3C) Fragments and Its specific antibody 10C9," J. Biol. Chem. 2008, 283, 19440-19447.
  14. K. Nabatame, M. Hirama, M. Inoue, "A Simple Desymmetrization Approach to the Framework of Spiroxins," Heterocycles 2008, 76, 1011-1016.
  15. K. Tsumoto, A. Yokota, Y. Tanaka, M. Ui, T. Tsumuraya, I. Fujii, I. Kumagai, Y. Nagumo, H. Oguri, M. Inoue, M. Hirama, "Critical contribution of aromatic rings to specific recognition of polyether rings.: The case of ciguatoxin CTX3C-ABC and its specific antibody 1C49," J. Biol. Chem. 2008, 283, 12259-12266
  16. M. Inoue, I. Ohashi, T. Kawaguchi, M. Hirama, "Total Synthesis of the C-1027 Chromophore Core: Extremely Facile Enediyne Formation through SmI2-Mediated 1,2-Elimination," Angew. Chem. Int. Ed. 2008, 47, 1777-1779.
  17. K. Iso, M. Inoue, N. Kato, M. Hirama, "Synthesis of the Bicyclo[7.3.0]dodecadiyne Core of the Maduropeptin Chromophore," Chem. Asian J. 2008, 3, 447-453.
  18. K. Komano, S. Shimamura, M. Inoue, M. Hirama, "Total Synthesis of the Maduropeptin Chromophore Aglycon," J. Am. Chem. Soc. 2007, 129, 14184-14186.
  19. M. Inoue, N. Lee, S. Kasuya, T. Sato, M. Hirama, M. Moriyama, Y. Fukuyama, "Total Synthesis and Bioactivity of an Unnatural Enantiomer of Merrilactone A: Development of an Enantioselective Desymmetrization Strategy," J. Org. Chem. 2007, 72, 3065-3075.
  20. M. Inoue, M. Iwatsu, S. Yamashita, M. Hirama, "A Concise Route to Two Distinct E-Ring Structures of Ciguatoxins," Heterocycles 2007, 72, 327-338.
  21. M. Inoue, F. Saito, M. Iwatsu, Y. Ishihara, M. Hirama,　"Convergent Synthesis of the ABCDE-Ring Fragment of the Caribbean Ciguatoxin C-CTX-1," Tetrahedron Lett. 2007, 48, 2177-2180.
  22. K. Yoshikawa, M. Inoue, M. Hirama, "Synthesis of the LMN-Ring Fragment of the Caribbean Ciguatoxin C-CTX-1," Tetrahedron Lett. 2007, 48, 2171-2175.
  23. M. Inoue, S. Yamashita, Y. Ishihara, M. Hirama, "Two Convergent Routes to the Left Wing Fragment of Ciguatoxin CTX3C Using O,S-Acetals As Key Intermediates," Org. Lett. 2006, 8, 5805-5808.
  24. M. Inoue, Y. Ishihara, S. Yamashita, M. Hirama, "Convergent Assembly of Polycyclic Ethers via Acyl Radical Addition to Unactivated Enol Ether," Org. Lett. 2006, 8, 5801-5804.
  25. V. Ghiaroni, H. Fuwa, M. Inoue, M. Sasaki, M. Hirama, T. Yasumoto, G. P. Rossini, G. Scalera,P. Pietra A. Bigiani, "Effect of Ciguatoxin 3C on Voltage-Gated Na+ and K+ Currents in Mouse Taste Cells," Chem. Senses 2006, 31, 673-680.
  26. T. Tsumuraya, I. Fujii, M. Inoue, A. Tatami, K. Miyazaki, M. Hirama, "Production of monoclonal antibodies for sandwich immunoassay detection of ciguatoxin 51-hydroxyCTX3C," Toxicon 2006, 48, 287-294.
  27. M. Inoue, K. Miyazaki, Y. Ishihara, A. Tatami, Y. Ohnuma, Y. Kawada, K. Komano, S. Yamashita, N. Lee, M. Hirama, "Total Synthesis of Ciguatoxin and 51-HydroxyCTX3C," J. Am. Chem. Soc. 2006, 128, 9352-9354.
  28. M. Inoue, T. Takahashi, H. Furuyama, M. Hirama, "Structural Factors Governing Stereoselective Heck Reaction for the Construction of the Oxindole Portion of TMC-95A," Synlett 2006, 3037-3040.
  29. M. Inoue, T. Sato, M. Hirama, "Asymmetric Total Synthesis of (-)-Merrilactone A: Use of a Bulky Protective Group as Long-Range Stereocontrolling Element," Angew. Chem. Int. Ed. 2006, 45, 4843-4848.
  30. M. Inoue, T. Usuki, N. Lee, M. Hirama, T. Tanaka, F. Hosoi, S. Ohie, T. Otani, "Antitumor Enediyne Chromoprotein C-1027: Mechanistic Investigation of the Chromophore-Mediated Self-Decomposition Pathway," J. Am. Chem. Soc. 2006, 128, 7896-7903.
  31. T. Usuki, M. Inoue, K. Akiyama, M. Hirama, "ESR Studies on the DNA Cleavage Induced by Enediyne C-1027 Chromophore," Bioorg. & Med. Chem. 2005, 13, 5218-5224.
  32. S. Sakamoto, H. Sakazaki, K. Hagiwara, K. Kamada, K. Ishii, T. Noda, M. Inoue, M. Hirama, "A Formal Total Synthesis of (+)-Pinnatoxin A," Angew. Chem. Int. Ed. 2004, 43, 6505-6510.
  33. M. Inoue, T. Sasaki, S. Hatano, M. Hirama, "Synthesis of the C-1027 Chromophore Framework through Atropselective Macrolactonization," Angew. Chem. Int. Ed. 2004, 43, 6500-6505.
  34. M. Inoue, S. Hatano, M. Kodama, T. Sasaki, T. Kikuchi, M. Hirama, "Synthesis of the Bicyclo[7.3.0]dodecatrienediyne Core of the C-1027 Chromophore," Org. Lett. 2004, 6, 3833-3836.
  35. M. Inoue, T. Kikuchi, M. Hirama, "Synthesis of the Fully Functionalized Nine-membered Diyne Core of the C-1027 Chromophore," Tetrahedron Lett. 2004, 45, 6439-6442.
  36. T. Usuki, T. Mita, M. J. Lear, P. Das, F. Yoshimura, M. Inoue, M. Hirama, K. Akiyama, S. Tero-Kubota, "Spin-Trapping of 13C-Labeled p-Benzynes, Generated via the Masamune-Bergman Cyclization of Bicyclic Nine-Membered Enediynes," Angew. Chem. Int. Ed. 2004, 43, 5249-5253.
  37. M. Inoue, K. Miyazaki, H. Uehara, M. Maruyama, M. Hirama, "First and Second Generation Total Synthesis of Ciguatoxin CTX3C," Proc. Natl. Acad. Sci. U.S.A. 2004, 101, 12013-12018.
  38. K. Yamaoka, M. Inoue, H. Miyahara, K. Miyazaki, M. Hirama, "A Quantitative and Comparative Study of the Effects of a Synthetic Ciguatoxin CTX3C on the Kinetic Properties of Voltage-dependent Sodium Channels," Br. J. Pharmacol. 2004, 142, 879-889.
  39. M. Inoue, S. Yamashita, A. Tatami, K. Miyazaki, M. Hirama, "A New Stereoselective Synthesis of Ciguatoxin Right Wing Fragments," J. Org. Chem. 2004, 69, 2797-2804.
  40. M. Inoue, S. Yamashita, M. Hirama, "A New Synthesis of Key Intermediates for the Assembly of Polycyclic Ethers: Yb(OTf)3-promoted Formation of O,S-Acetals from -Fluorosulfides and Alcohols," Tetrahedron Lett. 2004, 45, 2053-2056.
  41. T. Usuki, M. Inoue, M. Hirama, T. Tanaka, "Rational Design of a Supra C-1027: Kinetically Stabilized Analogue of the Antitumor Enediyne Chromoprotein ," J. Am. Chem. Soc. 2004, 126, 3022-3023.
  42. M. Inoue, H. Zhai, H. Sakazaki, H. Furuyama, Y. Fukuyama, M. Hirama, "TMC-95A, a Reversible Proteasome Inhibitor, Induces Neurite Outgrowth in PC12 Cells," Bioorg. Med. Chem. Lett. 2004, 14, 663-665.
  43. M. Inoue, T. Sato, M. Hirama, "Total Synthesis of Merrilactone A," J. Am. Chem. Soc. 2003, 125, 10772-10773.
  44. M. Inoue, J. Wang, G.-X. Wang, Y. Ogasawara, M. Hirama, "Divergent Synthesis of the Tetracyclic Ethers of 6-X-7-6 Ring System," Tetrahedron 2003, 59, 5645-5659.
  45. A. Tatami, M. Inoue, H. Uehara, M. Hirama, "A Concise Route to the Right Wing of Ciguatoxin," Tetrahedron Lett. 2003, 44, 5229-5233.
  46. M. Inoue, H. Sakazaki, H. Furuyama, M. Hirama, "Total Synthesis of TMC-95A," Angew. Chem. Int. Ed. 2003, 42, 2654-2657.
  47. M. Inoue, M. Hirama, M. Satake, K. Sugiyama, T. Yasumoto, "Inhibition of Brevetoxin Binding to the Voltage-gated Sodium Channel by Gambierol and Gambieric Acid-A," Toxicon 2003, 41, 469-474.
  48. M. Inoue, K. Nabatame, M. Hirama, "A Novel Route to 1,8-Dihydroxynaphthalene-derived Natural Products. Synthesis of (±)-CJ-12,372," Heterocycles 2003, 59, 87-92.
  49. M. Inoue, H. Uehara, M. Maruyama, M. Hirama, "Practical Total Synthesis of Ciguatoxin CTX3C by Improved Protective Group Strategy," Org. Lett. 2002, 4, 4551-4554.
  50. M. Inoue, G. X. Wang, J. Wang, M. Hirama, "Novel Assembly of Cyclic Ethers by Coupling -Chlorosulfides and Alcohols," Org. Lett. 2002, 4, 3439-3442.
  51. T. Usuki, M. Inoue, K. Akiyama, M. Hirama, "Spin-trapping Study of DNA Cleavage Induced by Enediyne C-1027 Chromophore," Chem. Lett. 2002, 1148.
  52. S. Nozaki, Y. Tomioka, T. Hishinuma, M. Inoue, Y. Nagumo, L. R. .Tsuruta, K. Hayashi, T. Matsumoto, Y. Kato, S. Ishiwata, K. Itoh, T. Suzuki, M. Hirama, M. Mizuzaki, "Design, Production, and Characterization of Recombinant Neocarzinostatin Apoprotein in Escherichia coli," J. Biochem. 2002, 131, 729-738.
  53. H. Uehara, T. Oishi, M. Inoue, M. Shoji, Y. Nagumo, M., Kosaka, J.-.Y. Le Brazidec, M. Hirama, "Convergent Synthesis of the HIJKLM Ring Fragment of Ciguatoxin CTX3C," Tetrahedron Symposia-in-Print 2002, 58, 6493-6512.
  54. M. Maruyama, M. Inoue, T. Oishi, H. Oguri, Y. Ogasawara, Y. Shindo, M. Hirama, "Convergent Synthesis of the ABCDE Ring System of Ciguatoxin CTX3C," Tetrahedron Symposia-in-Print 2002, 58, 1835-1851.
  55. M. Hirama, T. Oishi, H. Uehara, M. Inoue, M. Maruyama, H. Oguri, M. Satake, "Total Synthesis of Ciguatoxin CTX3C," Science 2001, 294, 1904-1907.
  56. M. Inoue, H. Furuyama, H. Sakazaki, M. Hirama, "Stereocontrolled Synthesis of the Nothern Part of Potent Proteasome Inhibitor TMC-95A," Org. Lett. 2001, 3, 2863-2865.
  57. H. Imai, H. Uehara, M. Inoue, H. Oguri, T. Oishi, M. Hirama, "Convergent Synthesis of the EFGH Ring Fragment of Ciguatoxin CTX3C," Tetrahedron Lett. 2001, 42, 6219-6222.
  58. T. Sasaki, M. Inoue, M. Hirama, "Synthetic Stidies toward C-1027 Chromophore: Construction of a Highly Unsaturated Macrocycle," Tetrahedron Lett. 2001, 42, 5299-5303.
  59. M. Inoue, M. D. Carson, A. J. Frontier, S. J. Danishefsky, "Total Synthesis and Determination of the Absolute Configuration of Frondosin B," J. Am. Chem. Soc. 2001, 123, 1878-1889.
  60. M. Inoue, A. J. Frontier, S. J. Danishefsky, "The Total Synthesis of Frondosin B," Angew. Chem. Int. Ed. 2000, 39, 761-764.
  61. T. P. P. Petus, M. Inoue, X.-T. Chen, S. J. Danishefsky, "A Fully Synthetic Route to the Neurotrophic Illicinones: Synthesis of Tricycloillicinone and Bicycloillicinone Aldehyde," J. Am. Chem. Soc. 2000, 122, 6160-6168.
  62. S. Pauillac, M. Sasaki, M. Inoue, J. Naar, P. Branaa, M. Chinain, K. Tachibana, A.-M. Legrand, "Characterization of Mice Antisera Elicited with a Ciguatoxin Tetracyclic Synthetic Ring Fragment (JKLM) Conjugated to Carrier Proteins," Toxicon 2000, 38, 669-685.
  63. M. Inoue, M. Sasaki, K. Tachibana, "A Convergent Synthesis of Decacyclic Ciguatoxin Model Containing the F-M Ring Framework," J. Org. Chem. 1999, 64, 9416-9429.
  64. M. Sasaki, M. Inoue, K. Takamatsu, K. Tachibana, "Stereocontrolled Synthesis of the JKLM Ring Fragment of Ciguatoxin," J. Org. Chem. 1999, 64, 9399-9415.
  65. M. Inoue, M. Sasaki, K. Tachibana, "A Convergent Synthesis of the trans-Fused Hexahydrooxonine Ring System and Reproduction of Conformational Behavior Shown by Ring F of Ciguatoxin," Tetrahedron 1999, 55, 10949-10970.
  66. M. Sasaki, H. Fuwa, M. Inoue, K. Tachibana, "New Strategy for Convergent Synthesis of trans-Fused Polyether Frameworks Based on Palladium-Catalyzed Suzuki Cross-Coupling Reaction," Tetrahedron Lett. 1998, 39, 9027-9030.
  67. M. Sasaki, M. Inoue, T. Noguchi, A. Takeichi, K. Tachibana, "Convergent and Stereoselective Method for Synthesis of O-Linked Oxepane Ring System by Intramolecular Radical Cyclization," Tetrahedron Lett. 1998, 39, 2783-2786.
  68. M. Inoue, M. Sasaki, K. Tachibana, "Synthetic Studies on Ciguatoxin: A Convergent Strategy for Construction of the F-M Ring Framework," Angew. Chem. Int. Ed. 1998, 37, 965-969.
  69. M. Inoue, M. Sasaki, K. Tachibana, "Construction of Fused Oxonene Ring and Reproduction of Conformational Behavior Shown by Ring F of Ciguatoxin," Tetrahedron Lett. 1997, 38, 1611-1614.
  70. M. Sasaki, M. Inoue, K. Tachibana, "Synthetic Studies toward Ciguatoxin. Stereocontrolled Construction of the KLM Ring Fragment," J. Org. Chem. 1994, 59, 715-717.
Reviews and Accounts
  1. S. Matsuoka, M. Inoue, "Application of REDOR NMR in Natural Product Chemistry," Chem. Commun. 2009, 5664-5675.
  2. D. Urabe, M. Inoue, "Total Syntheses of Sesquiterpenes from Illicium Species," Tetrahedron 2009, 65, 6271-6289.
  3. M. Inoue, T. Sato, M. Hirama "Total Synthesis of Merrilactone A: Long-Range Stereocontrol and Asymmetric Desymmetrization." Journal of Synthetic Organic Chemistry, Japan 2007, 65, 419-429. (in Japanese)
  4. M. Inoue, "Exploring the Chemistry and Biology of Antitumor Enediyne Chromoprotein C-1027," Bull. Chem. Soc. Jpn. 2006, 79, 501-510.
  5. M. Inoue, "Convergent Strategies for Syntheses of trans-Fused Polycyclic Ethers," Chem. Rev. 2005, 105, 4379-4405.
  6. M. Inoue, M. Hirama, "Evolution of a Practical Total Synthesis of Ciguatoxin CTX3C," Acc. Chem. Res. 2004, 37, 961-968.
  7. M. Inoue, "Convergent Syntheses of Polycyclic Ethers. Illustrations of the Utility of Acetal-linked Intermediates," Org. Biomol. Chem. 2004, 2, 1811-1817.
  8. M. Inoue, M. Hirama, "Total Synthesis of Ciguatoxin CTX3C, a Causative Toxin of Ciguatera Seafood Poisoning," Synlett 2004, 577-595.
  9. M. Sasaki, M. Inoue, "Synthetic studies on polyether natural products: New synthetic methods for construction of medium-sized cyclic ethers and convergent coupling of polyether fragments." Journal of Synthetic Organic Chemistry, Japan 2001, 59, 193-205. (in Japanese) .
Book Chapters
  1. M. Inoue , S. Yamashita, "Product Class: 5-, 6- and Larger Ring Oxacycloalkanes," Science of Synthesis, ed. by C. J. Forsyth, Thieme, Chapter 37.5, in press.
  2. S. J. Danishefsky, M. Inoue, D. Trauner, "Synthesis of Immunomodulatory Marine Natural Products," The Role of Natural Products in Drug Discovery, eds. by J. Mulzer, R. Bohlmann, Springer-Verlag, 2000, pp. 1-24.
Daisuke Urabe
Original Papers
  1. C. Dong, J. A. Henderson, Y. Kaburagi, T. Sasaki, D. Kim, J. T. Kim, D. Urabe, H. Guo, Y. Kishi, "New Syntheses of E7389 C14-C35 and Halichondrin C14-C38 Building Blocks: Reductive Cyclization and Oxy-Michael Cyclization Approaches," J. Am. Chem. Soc. 2009, 131, 15642-15646
  2. H. Guo, C. Dong, Kim, D. Urabe, J. Wang, J. T. Kim, X. Liu, T. Sasaki, Y. Kishi, "Toolbox Approach to the Search for Effective Ligands for Catalytic Asymmetric Cr-Mediated Coupling Reactions," J. Am. Chem. Soc. 2009, 131, 15387-15393
  3. S. Ogawa, D. Urabe, Y. Yokokura, H. Arai, M. Arita, M. Inoue, "Total Synthesis and Bioactivity of Resolvin E2," Org. Lett. 2009, 11, 3602-2605.
  4. T. Nishikawa, D. Urabe, M. Isobe, "Synthesis of N-Acylisoxazolidine Derivatives, Related to a Partial Structure Found in Zetekitoxin AB, a Golden Frog Poison," Heterocycles 2009, 79, 379-385.
  5. T. Nishikawa, D. Urabe, M. Tomita, T. Tsujimoto, T. Iwabuchi, M. Isobe, "One-Pot Transformation of Trichloroacetamide into Readily Deprotectable Carbamates," Org. Lett. 2006, 8, 3263-3265.
  6. D. Urabe, T. Nishikawa, M. Isobe, "An Efficient Total Synthesis of Optically Active Tetrodotoxin from Levoglucosenone," Chem. Asian J. 2006, 1, 125-135.
  7. T. Tsujimoto, T. Nishikawa, D. Urabe, M. Isobe, "Synthesis of Functionalized Cyclopentane for Pactamycin, a Potent Antitumor Antibiotic," Synlett 2005, 433-436.
  8. D. Urabe, K. Sugino, T. Nishikawa, M. Isobe, "A Novel Deprotection of Trichloroacetamide," Tetrahedron Lett. 2004, 45, 9405-9407.
  9. T. Nishikawa, D. Urabe, M. Isobe, "An Efficient Total Synthesis of Optically Active Tetrodotoxin," Angew. Chem. Int. Ed. 2004, 43, 4782-4785.
  10. T. Nishikawa, D. Urabe, K. Yoshida, T. Iwabuchi, M. Asai, M. Isobe, "Stereocontrolled Synthesis of 8,11-Dideoxytetrodotoxin, Unnatural Analogue of Puffer Fish Toxin," Chem. Eur. J. 2004, 10, 452-462.
  11. M. Yotsu-Yamashita, D. Urabe, M. Asai, T. Nishikawa, M. Isobe, "Biological Activity of 8,11-Dideoxytetrodotoxin: Lethality to Mice and Inhibitory Activity to Cytotoxicity of Ouabain and Veratridine in Mouse Neuroblastoma Cells, Neuro-2a," Toxicon 2003, 42, 557-560.
  12. T. Nishikawa, D. Urabe, K. Yoshida, T. Iwabuchi, M. Asai, M. Isobe, "Total Syntheses of 11-Deoxytetrodotoxin and 8,11-Dideoxytetrodotoxin," Pure Appl. Chem. 2003, 75, 251-257.
  13. T. Nishikawa, D. Urabe, K. Yoshida, T. Iwabuchi, M. Asai, M. Isobe, "Stereocontrolled Synthesis of 8,11-Dideoxytetrodotoxin, Unnatural Analog of Puffer Fish Toxin," Org. Lett. 2002, 4, 2679-2682.
Reviews and Accounts
  1. D. Urabe, M. Inoue, "Total Syntheses of Sesquiterpenes from Illicium Species," Tetrahedron 2009, 65, 6271-6289.
  2. D. Urabe, "Total Syntheses of Saxitoxin and its Analogues." Journal of Synthetic Organic Chemistry, Japan 2009, 67, 248-249. (in Japanese) .
Shin Kamijo
Original Papers
  1. S. Kamijo, Y. Amaoka, M. Inoue, "Manganese-Catalyzed Direct Oxidation of Methyl Ethers to Ketones," Chem. Asian J. Early view.
  2. S. Kamijo, T. Hoshikawa, M. Inoue, "Regio- and Stereoselective Acylation of Saturated Carbocycles via Norrish-Yang Photocyclization," Tetrahedron Lett. 2010, 51, 872-874.
  3. S. Kasuya, S. Kamijo, M. Inoue, "Direct Construction of 1,3-Diaxial Diol Derivatives by C-H Hydroxylation," Org. Lett. 2009, 11, 3630-3632.
  4. K. Yamatsugu, L. Yin, S. Kamijo, M. Kanai, M. Shibasaki, "A Synthesis of Tamiflu by Using a Barium-Catalyzed Asymmetric Diels-Alder-Type Reaction," Angew. Chem. Int. Ed. 2009, 48, 1070-1076.
  5. T. Jin, F. Kitahara, S. Kamijo, Y. Yamamoto, "Synthesis of 5-Substituted 1H-Tetrazoles by the Copper-Catalyzed [3+2] Cycloaddition of Nitliles and Trimethylsilyl Azide," Chem. Asian J. 2008, 3, 1575-1580.
  6. T. Jin, F. Kitahara, S. Kamijo, Y. Yamamoto, "Copper-Catalyzed Synthesis of 5-Substituted 1H-Tetrazoles via the [3+2] Cycloaddition of Nitriles and Trimethylsilyl Azide," Tetrahedron Lett. 2008, 49, 2824-2827.
  7. S. Kamijo, Y. Yamamoto, "Recent Progress in the Catalytic Synthesis of Imidazoles," Chem. Asian J. 2007, 2, 568-578.
  8. K. Yamatsugu, S. Kamijo, Y. Suto, M. Kanai, M. Shibasaki, "A concise synthesis of Tamiflu: The third generation route via the Diels-Alder reaction and the Curtius rearrangement," Tetrahedron Lett. 2007, 48, 1403-1406.
  9. C. Kanazawa, S. Kamijo, Y. Yamamoto, "Synthesis of Imidazoles through the Copper-Catalyzed Cross-Cycloaddition between Two Different Isocyanides," J. Am. Chem. Soc. 2006, 127, 10662-10663.
  10. S. Kamijo, G. B. Dudley, "Cyclic vinylogous triflate hemiacetals as new surrogates for alkynyl aldehydes," Tetrahedron Lett. 2006, 47, 5629-5632.
  11. S. Kamijo, G. B. Dudley, "Tandem Nucleophilic Addition/Fragmentation Reactions and Synthetic Versatility of Vinylogous Acyl Triflates," J. Am. Chem. Soc. 2006, 127, 6499-6507.
  12. D. M. Jones, S. Kamijo, G. B. Dudley, "Grignard-Triggered Fragmentation of Vinylogous Acyl Triflates: Synthesis of (Z)-6-Heneicosen-11-one, the Douglas Fir Tussock Moth Sex Pheromone," Synlett 2006, 936-938.
  13. S. Kamijo, G. B. Dudley, "Claisen-Type Condensation of Vinylogous Acyl Triflates," Org. Lett. 2006, 8, 175-177.
  14. S. Kamijo, Y. Sasaki, C. Kanazawa, T. Schüβeler, Y. Yamamoto, "Oxindole Synthesis through Intramolecular Nucleophilic Addition of Vinylpalladiums to Aryl Isocyanates," Angew. Chem., Int. Ed. 2005, 44, 7718-7721.
  15. S. Kamijo, Z. Huo, T. Jin, C. Kanazawa, Y. Yamamoto, "Facile Deallylation Protocols for the Preparation of N-Unsubstituted Triazoles and Tetrazoles," J. Org. Chem. 2005, 70, 6389-6397.
  16. S. Kamijo, C. Kanazawa, Y. Yamamoto, "Copper- or Phosphine-Catalyzed Reaction of Alkynes with Isocyanides. Regioselective Synthesis of Substituted Pyrroles Controlled by the Catalysts," J. Am. Chem. Soc. 2005, 127, 9260-9266.
  17. S. Kamijo, G. B. Dudley, "A Tandem Carbanion Addition/Carbon-Carbon bond Cleavage Reaction Yields Alkynyl Ketones," J. Am. Chem. Soc. 2005, 127, 5028-5029.
  18. S. Kamijo, C. Kanazawa, Y. Yamamoto, "Phosphine-catalyzed regioselective heteroaromatization between activated alkynes and isocyanides leading to pyrroles," Tetrahedron Lett. 2005, 46, 2563-2566.
  19. T. Jin, S. Kamijo, Y. Yamamoto, "Synthesis of 1-substituted tetrazoles via the acid-catalyzed [3+2] cycloaddition between isocyanides and trimethylsilyl azide," Tetrahedron Lett. 2004, 45, 9435-9437.
  20. T. Jin, S. Kamijo, Y. Yamamoto, "Copper-Catalyzed Synthesis of N-Unsubstituted 1,2,3-Triazoles from Nonactivated Terminal Alkynes," Eur. J. Org. Chem. 2004, 3789-3791.
  21. S. Kamijo, Y. Yamamoto, "New Catalytic Reactions via the π Allylpalladium Azide Complexes," J. Syn. Org. Chem. Jpn. 2004, 62, 682-692.
  22. S. Kamijo, T. Jin, Z. Huo, Y. Yamamoto, "A One-Pot Procedure for the Regiocontrolled Synthesis of Allyltriazoles via the Pd-Cu Bimetallic Catalyzed Three-Component Coupling Reaction of Nonactivated Terminal Alkynes, Allyl Carbonate, and Trimethylsilyl Azide," J. Org. Chem. 2004, 69, 2386-2393.
  23. S. Kamijo, T. Jin, Y. Yamamoto, "Four-component coupling reactions of silylacetylenes, allyl carbonates, and trimethylsilyl azide catalyzed by a Pd(0)-Cu(I) bimetallic catalyst. Fully substituted triazole synthesis from seemingly internal alkynes," Tetrahedron Lett. 2004, 45, 689-691.
  24. S. Kamijo, Y. Sasaki, Y. Yamamoto, "Copper-catalyzed tandem reaction between imines and alcohols leading to indoles," Tetrahedron Lett. 2004, 45, 35-38.
  25. S. Kamijo, T. Jin, Z. Huo, Y. S. Gyoung, J.-G. Shim, Y. Yamamoto, "Tetrazole Synthesis via the Palladium-Catalyzed Three Component Coupling Reaction," Molecular Diversity 2003, 6, 181-192.
  26. S. Kamijo, T. Jin, Z. Huo, Y. Yamamoto, "Synthesis of Triazoles from Nonactivated Terminal Alkynes via the Three-Component Coupling Reaction using a Pd(0)-Cu(I) Bimetallic Catalyst," J. Am. Chem. Soc. 2003, 125, 7786-7787.
  27. S. Kamijo, Y. Yamamoto, "A Bimetallic Catalyst and Dual Role Catalyst: Synthesis of N-(Alkoxycarbonyl)indoles from 2-(Alkynyl)phenylisocyanates," J. Org. Chem. 2003, 68, 4764-4771.
  28. S. Kamijo, T. Jin, Z. Huo, Y. Yamamoto, "Regiospecific synthesis of 2-allyl-1,2,3-triazoles by palladium-catalyzed 1,3-dipolar cycloaddition," Tetrahedron Lett. 2002, 43, 9707-9710.
  29. S. Kamijo, T. Jin, Y. Yamamoto, "Palladium-Catalyzed Selective Synthesis of 2-Allyltetrazoles," J. Org. Chem. 2002, 67, 7413-7417.
  30. S. Kamijo, Y. Yamamoto, "Synthesis of Allyl Cyanamides and N-Cyanoindoles via the Palladium-Catalyzed Three-Component Coupling Reaction," J. Am. Chem. Soc. 2002, 124, 11940-11945.
  31. S. Kamijo, Y. Yamamoto, "A New Pd0-CuI Bimetallic Catalyst System for the Synthesis of Indoles from Isocyanates and Allyl Carbonates," Angew. Chem., Int. Ed. 2002, 41, 3230-3233.
  32. S. Kamijo, T. Jin, Y. Yamamoto, "Cyanamide Synthesis by the Palladium-Catalyzed Cleavage of a Si-N Bond," Angew. Chem., Int. Ed. 2002, 41, 1780-1782.
  33. S. Kamijo, T. Jin, Y. Yamamoto, "Novel Synthetic Route to Allyl Cyanamides: Palladium-Catalyzed Coupling of Isocyanides, Allyl Carbonate, and Trimethylsilyl Azide," J. Am. Chem. Soc. 2001, 123, 9453-9454.
  34. P. W. H. Chan, S. Kamijo, Y. Yamamoto, "Lewis Acid Catalyzed Reaction of Aromatic Vinyl Halides with Aromatic Aldehydes: A Novel Aldol-type Condensation Mimic," Synlett 2001, 910-913.
  35. A. Takeda, S. Kamijo, Y. Yamamoto, "Indole Synthesis via Palladium-Catalyzed Intramolecular Cyclization of Alkynes and Imines," J. Am. Chem. Soc. 2000, 122, 5662-5663.
  36. S. Kamijo, Y. Yamamoto, "Synthesis of Cyclic Ethers via the Palladium Catalyzed Intramolecular Hydrocarbonation of Alkoxyallenes," Tetrahedron Lett. 1999, 40, 1747-1750.
  37. S. Kamijo, M. Al-Masum, Y. Yamamoto, "Palladium Catalyzed Hydrosulfination of Allenes with Tosylhydrazine Leading to Allylsulfones," Tetrahedron Lett. 1998, 39, 691-694.
  38. M. Meguro, S. Kamijo, Y. Yamamoto, "Palladium Catalyzed Intramolecular Hydrocarbonation of Allenes Leading to Carbocycles," Tetrahedron Lett. 1996, 37, 7453-7456
Book Chapters
  1. S. Kamijo, Y. Yamamoto, "Organic Synthesis with Bimetallic Systems," In Multimetallic Catalysts in Organic Synthesis, eds. by M. Shibasaki, Y. Yamamoto, Wiley-VCH: Weinheim, 2004, Chap. 1.
Shigeru Matsuoka
Original Papers
  1. M. Inoue, N. Shinohara, S. Tanabe, T. Takahashi, K. Okura, H. Itoh, Y. Mizoguchi, M. Iida, N. Lee, S. Matsuoka, "Total synthesis of the large non-ribosomal peptide polytheonamide B," Nature Chem. AOP.
  2. K. Okura, S. Matsuoka, R. Goto, M. Inoue, "The Twisted Side Chain of Antillatoxin is Important for Potent Toxicity: Total Synthesis and Biological Evaluation of Antillatoxin and Analogues," Angew. Chem. Int. Ed. 2010, 49, 329-332.
  3. K. Matoba, T. Nara, T. Aoki, T. Honma, A. Tanaka, M. Inoue, S. Matsuoka, D. Inaoka, K. Kita, S. Harada, "Crystallization and Preliminary X-ray Analysis of Aspartate Transcarbamoylase from the Parasitic Protist Trypanosoma Cruzi," Acta Crystallogr., Sect. F: Struct. Biol. Cryst. Commun. 2009, F65, 933.
  4. M. Inoue, N. Lee, K. Miyazaki, T. Usuki, S. Matsuoka, M. Hirama "Critical Importance of the Nine-Membered F Ring of Ciguatoxin for Potent Bioactivity: Total Synthesis and Biological Evaluation of F-Ring-Modified Analogues" Angew. Chem. Int. Ed. 2008, 47, 8611-8614.
  5. S. J. Kim, S. Matsuoka, G. J. Patti, J. Schaefer, "Vancomycin Derivative with Damaged d-Ala-d-Ala Binding Cleft Binds to Cross-linked Peptidoglycan in the Cell Wall of Staphylococcus aureus," Biochemistry 2008, 47, 3822-3831.
  6. Y. Kasai, N. Matsumori, Y. Umegawa, S. Matsuoka, H. Ueno, H. Ikeuchi, T. Oishi, M. Murata, "Self-Assembly of Amphotericin B is Probably Surrounded by Ergosterol; Bimolecular Interactions as Evidenced by Solid State NMR and CD Spectra," Chem. Eur. J. 2008, 14, 1178-1185.
  7. S. Matsuoka, J. Schaefer, "Dipolar Double-Quantum Filtered Rotational-Echo Double Resonance," Magn. Reson. Chem. 2007, 45, S61-S64.
  8. S. Matsuoka, J. Schaefer, "Double-Quantum Filtered Rotational-Echo Double Resonance," J. Magn. Reson. 2006, 183, 271-277.
  9. S. Matsuoka, H. Ikeuchi, Y. Umegawa, N. Matsumori, M. Murata, "Membrane Interaction of Amphotericin B as Single-Length Assemble Examined by Solid State NMR for Uniformly 13C-Labeled Agent," Bioorg. Med. Chem. 2006, 14, 6608-6614.
  10. N. Morsy, T. Houdai, S. Matsuoka, N. Matsumori, S. Adachi, T. Oishi, M. Murata, T. Iwashita, T. Fujita, "Structures of new amphidinols with truncated polyhydroxyl chain and their membrane-permeabilizing activities," Bioorg. Med. Chem. 2006, 14, 6548-6554.
  11. N. Morsy, S. Matsuoka, T. Houdai, N. Matsumori, S. Adachi, M. Murata, T. Iwashita, T. Fujita, "Isolation and structure elucidation of a new amphidinol with a truncated polyhydroxyl chain from Amphidinium klebsii," Tetrahedron 2005, 61, 8606-8610.
  12. M. Mori, T. Oishi, S. Matsuoka, N. Matsumori, M. Murata, M. Satake, Y. Ohshima, N. Matsushita, S. Aimoto, "Ladder-shaped polyether compound, desulfated yessotoxin, interacts with membrane-integral -helix peptides," Bioorg. Med. Chem. 2005, 13, 5099-5103.
  13. T. Houdai, S. Matsuoka, N. Morsy, N. Matsumori, M. Satake, M. Murata, "Hairpin conformation of amphidinols possibly accounting for potent membrane permeabilizing activities," Tetrahedron 2005, 61, 2795-2802.
  14. S. Matsuoka, H. Ikeuchi, N. Matsumori, M. Murata, "Dominant Formation of Single-length Channel by Amphotericin B in Dimyristoylphosphatidylcholine Membrane Evidenced by 13C-31P REDOR," Biochemistry 2005, 44, 704-710.
  15. T. Houdai, S. Matsuoka, N. Matsumori, M. Murata, "Membrane-permeabilizing activities of amphidinol 3, polyene-polyhydroxy antifungal from a marine dinoflagellate," Biochim. Biophys. Acta 2004, 1667, 91-100.
  16. N. Matsumori, N. Eiraku, S. Matsuoka, T. Oishi, M. Murata, T. Aoki, T. Ide, "An Amphotericin B-Ergosterol Covalent Conjugate with Powerful Membrane Permeabilizing Activity," Chem. Biol. 2004, 11, 673-679.
  17. S. Matsuoka, M. Murata, "Membrane Permeabilizing Activity of Amphotericin B was Affected by Chain Length of Phosphatidylcholine Added as Minor Constituent," Biochim. Biophys. Acta 2003, 1617, 109-115.
  18. S. Matsuoka, N. Matsumori, M. Murata, "Amphotericin B - phospholipid covalent conjugates: dependence of membrane-permeabilizing activity on acyl-chain length," Org. Biomol. Chem. 2003, 1, 3882-3884.
  19. S. Matsuoka, M. Murata, "Cholesterol markedly reduces ion permeability induced by membrane-bound amphotericin B," Biochim. Biophys. Acta 2002, 1564, 429-434.
  20. N. Yamaji, N. Matsumori, S. Matsuoka, T. Oishi, M. Murata, "Amphotericin B dimers with bisamide linkage bearing powerful membrane-permeabilizing activity," Org. Lett. 2002, 4, 2087-2089.
  21. N. Matsumori, N. Yamaji, S. Matsuoka, T. Oishi, M. Murata, "Amphotericin B Covalent Dimers Forming Sterol-Dependent Ion-Permeable Membrane Channels," J. Am. Chem. Soc. 2002, 124, 4180-4181.
  22. T. Houdai, S. Matsuoka, M. Murata, M. Satake, S. Ota, Y. Oshima, L. L. Rhodes, "Acetate labeling patterns of dinoflagellate polyketides, amphidinol 2, 3 and 4," Tetrahedron 2001, 57, 5551-5555.
  23. K. Akasaka, S. Shichijyukari, S. Matsuoka, M. Murata, H. Meguro, H. Ohrui, "Absolute Configuration of a Ceramide with a Novel Branched-chain Fatty acid Isolated from the Epiphytic Dinoflagellate, Coolia monotis," Biosci. Biotechnol. Biochem. 2000, 69, 1842-1846.
  24. M. Murata, S. Matsuoka, N. Matsumori, G. K. Paul, K. Tachibana, "Absolute Configuration of Amphidinol 3, the First complete Structure Determination from Amphidinol Homologues: Application of a New Configuration Analysis Based on Carbon-Hydrogen Spin-Coupling Constants," J. Am. Chem. Soc. 1999, 121, 870-871.
  25. I. Tanaka, S. Matsuoka, M. Murata, K. Tachibana, "A New Ceramide with a Novel Branched-Chain Fatty Acid Isolated from the Epiphytic Dinoflagellate Coolia monotis Meunier," J. Nat. Prod. 1998, 61, 685-688.
Reviews and Accounts
  1. S. Matsuoka, M. Inoue, "Application of REDOR NMR in Natural Product Chemistry," Chem. Commun. 2009, 5664-5675.
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